Selective multi-electron aggregation at a hypervalent iodine center by sequential disproportionation. Academic Article

abstract

• We demonstrate that sequential disproportionation reactions can enable selective aggregation of two- or four electron-holes at a hypervalent iodine center. Disproportionation of an anodically generated iodanyl radical affords an iodosylbenzene derivative. Subsequent iodosylbenzene disproportionation can be triggered to provide access to an iodoxybenzene. These results demonstrate multielectron oxidation at the one-electron potential by selective and sequential disproportionation chemistry.

authors

• Powers, David

published proceedings

• Chem Commun (Camb)

altmetric score

• 6.55

author list (cited authors)

• Thai, P., Frey, B. L., Figgins, M. T., Thompson, R. R., Carmieli, R., & Powers, D. C.

citation count

• 0

complete list of authors

• Thai, Phong||Frey, Brandon L||Figgins, Matthew T||Thompson, Richard R||Carmieli, Raanan||Powers, David C

publication date

• April 2023

publisher

• Royal Society of Chemistry (RSC)  Publisher

published in

• Chemical Communications  Journal

keywords

• 34 Chemical Sciences
• 3405 Organic Chemistry

PubMed Central ID

• 36939182

Digital Object Identifier (DOI)

• 10.1039/d3cc00549f

start page

• 4308

end page

• 4311

volume

• 59

issue

• 29

URL

• http://dx.doi.org/10.1039/d3cc00549f