SilylSilylene Interplay in Cationic PSiP Pincer Complexes of Platinum
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2015 American Chemical Society. Herein we report the synthesis and spectroscopic observation of a Pt complex featuring a P2Si= ligand containing a central silylene donor connected to phosphines via two o-arylene linkers. Species of the type (P2Si=)PtR undergo a net 1,2-migration of R from Pt to Si, which leads to highly unsaturated Pt cations displaying only a very distant interaction with the weakly coordinating carborane anion. (Chemical Equation Presented).
author list (cited authors)
DeMott, J. C., Gu, W., McCulloch, B. J., Herbert, D. E., Goshert, M. D., Walensky, J. R., Zhou, J., & Ozerov, O. V.
complete list of authors
DeMott, Jessica C||Gu, Weixing||McCulloch, Billy J||Herbert, David E||Goshert, Mitchell D||Walensky, Justin R||Zhou, Jia||Ozerov, Oleg V