A terminal palladium fluoride complex supported by an anionic PNP pincer ligand

abstract

• A terminal palladium (II) fluoride complex (FPNP)PdF (where FPNP is a an anionic fluoro-substituted diarylamido/bis(phosphine) pincer ligand) has been prepared and characterized spectroscopically and structurally. An X-ray diffraction study revealed an approximately square-planar environment about Pd and a short Pd-F bond distance. (FPNP)PdF reacted with silanes containing electron-withdrawing groups on Si by exchange of fluoride with one of the substituents on Si. An analysis of the 19F chemical shifts of both the Pd-bound fluoride and of the fluorines on the backbone of the FPNP ligand is provided. 2010 Elsevier B.V.

authors

• Ozerov, Oleg

published proceedings

• JOURNAL OF FLUORINE CHEMISTRY

author list (cited authors)

• Huacuja, R., Herbert, D. E., Fafard, C. M., & Ozerov, O. V.

citation count

• 12

complete list of authors

• Huacuja, Rafael||Herbert, David E||Fafard, Claudia M||Ozerov, Oleg V

publication date

• January 2010

publisher

• Elsevier  Publisher

published in

• Journal of Fluorine Chemistry  Journal

keywords

• Fluoride
• Palladium
• Phosphine
• Pincer
• Pnp

Digital Object Identifier (DOI)

• 10.1016/j.jfluchem.2010.07.010

start page

• 1257

end page

• 1261

volume

• 131

issue

• 11

URL

• http://dx.doi.org/10.1016/j.jfluchem.2010.07.010