Solubilizing Metal-Organic Frameworks for an In Situ IR-SEC Study of a CO2 Reduction Catalyst.

abstract

• Metal-organic frameworks (MOFs) are typically assembled by bridging metal centers with organic linkers for various applications, including providing robust support for heterogeneous catalysts for CO2 reduction. In this study, we have demonstrated the solubilization of a MOF tethered to a CO2-reducing electrocatalyst and studied its fundamental electrochemistry in THF solvent using infrared spectroelectrochemistry (IR-SEC). The fundamental electrochemical properties of this immobilized catalyst were compared to that of its homogeneous counterpart. This approach provides a foundation for future experimental studies to bridge the gap between homogeneous and heterogeneous electrocatalysis.

authors

• Bengali, Ashfaq
• Madrahimov, Sherzod

published proceedings

• ACS Appl Mater Interfaces

altmetric score

• 1.75

author list (cited authors)

• Chen, W., Fan, W. Y., Sohail, M., Madrahimov, S. T., & Bengali, A. A.

citation count

• 0

complete list of authors

• Chen, Wenmiao||Fan, Wai Yip||Sohail, Muhammad||Madrahimov, Sherzod T||Bengali, Ashfaq A

publication date

• April 2023

publisher

• American Chemical Society (ACS)  Publisher

published in

• ACS Applied Materials & Interfaces  Journal

keywords

• Carbon Dioxide Reduction
• Catalyst
• Electrocatalyst
• Infrared Spectroelectrochemistry (ir-sec)
• Mofs

PubMed Central ID

• 36943895

Digital Object Identifier (DOI)

• 10.1021/acsami.2c20157

start page

• 16593

end page

• 16597

volume

• 15

issue

• 13

URL

• http://dx.doi.org/10.1021/acsami.2c20157