On phosphorus chemical shift anisotropy in metal (IV) phosphates and phosphonates: A 31 P NMR experimental study. Academic Article uri icon

abstract

  • The phosphorus chemical shift anisotropies, 31 Pcs, and asymmetry parameters were measured by the 31 P{1 H} NMR experiments in static and low-frequency spinning samples of the zirconium phosphates and phosphonates and also in the mixed Zr (IV)/Sn (IV) phosphate/phosphonate material. The data obtained have shown a 111 connectivity in the HPO4 and PO3 groups, which does not change at modification and intercalation of the materials. The 31 Pcs values of the phosphonate groups (43-49ppm) significantly surpass the values characterizing the HPO4 groups (23-37ppm). The 31 P cs values obtained for the metal (IV) phosphates were discussed in terms of P-O distances. The 31 P chemical shift anisotropy parameters can help at elucidation of local structures in phosphate and phosphonate materials.

published proceedings

  • Magn Reson Chem

altmetric score

  • 1

author list (cited authors)

  • Bakhmutov, V. I., Contreras-Ramirez, A., Drake, H., & Zhou, H.

citation count

  • 1

complete list of authors

  • Bakhmutov, Vladimir I||Contreras-Ramirez, Aida||Drake, Hannah||Zhou, Hong-Cai

publication date

  • January 2023

publisher