Augmenting metallobasicity to modulate gold hydrogen bonding. Academic Article

abstract

• We report the synthesis and characterization of two phosphine gold carbinol species designed to support intramolecular AuH-O hydrogen bonding. Increasing the metallobasicity of gold through chloride to phenyl ligand substitution produced an observable increase in this hydrogen bond's strength which was analyzed experimentally and computationally.

authors

• Gabbai, Francois

published proceedings

• Chem Commun (Camb)

altmetric score

• 3.5

author list (cited authors)

• Maltz, L. T., Wilkins, L. C., & Gabbai, F. P.

citation count

• 3

complete list of authors

• Maltz, Logan T||Wilkins, Lewis C||Gabbaiï, François P

publication date

• August 2022

publisher

• Royal Society of Chemistry (RSC)  Publisher

published in

• Chemical Communications  Journal

keywords

• Chlorides
• Gold
• Hydrogen Bonding
• Methanol

PubMed Central ID

• 35943075

Digital Object Identifier (DOI)

• 10.1039/d2cc03328c

start page

• 9650

end page

• 9653

volume

• 58

issue

• 69

URL

• http://dx.doi.org/10.1039/d2cc03328c