Hydronium Ions on the Surface of a Partially Hydrolyzed -Zirconium Phosphate: Solid-State 2H and 31P MAS NMR Evidence. uri icon

abstract

  • Characterization of the -zirconium phosphates 1-D2Oh and 1-D2Oh/dr, partially hydrolyzed with D2O, by powder X-ray diffraction, scanning electron microscopy, and multinuclear solid-state NMR techniques led to an unprecedented observation of D3O+ ions located on the surface and stabilized by hydrogen bonds. These ions are formed after the surface phosphate groups have been lost.

published proceedings

  • Inorg Chem

author list (cited authors)

  • Bakhmutov, V. I., Drake, H. F., & Zhou, H.

citation count

  • 2

publication date

  • May 2022