Real-time isotopic methane detection using mid-infrared spectroscopy.
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A real-time, nondestructive mid-infrared (mid-IR) platform was proposed for isotopic methane detection. The measurement system consisted of a tunable mid-IR laser, a miniaturized gas chamber, and a mid-IR signal receiver. The isotope ratio of the 12CH4/13CH4 was identified by measuring the mid-IR spectrum at =3.2-3.5m.In-situ12CH4/13CH4 monitoring was then achieved by tracing the characteristic mid-IR absorption peaks assigned to the 12CH4 at =3.328m and 13CH4 at =3.340m. The real-time methane isotope analysis can be applied to environmental monitoring and petroleum industries.