A versatile metal-organic framework for carbon dioxide capture and cooperative catalysis.
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abstract
A multi-functional MOF was constructed from Cu paddlewheel motifs and a judiciously designed novel ligand bearing carboxylate, pyridine, and amide groups. exhibits selective adsorption of CO(2) over CH(4) and excellent catalytic activity in a tandem one-pot deacetalization-Knoevenagel condensation reaction as a cooperative catalyst.