Formation of an AgAl dative bond is avoided in reactions of an alane/tris(phosphine) ligand with monovalent silver. uri icon

abstract

  • An alane/tris(phospine) ligand reacts with AgOTf by coordination of three phosphines to the Ag center and transfer of triflate to the tris(pyrrolyl) Al site. Reaction with Ag[HCB11Cl11] results in the coordination of two phosphines to Ag and one to Al, with no significant Ag-Al bonding in either structure.

published proceedings

  • Dalton Trans

altmetric score

  • 1.5

author list (cited authors)

  • Lai, Q., Bhuvanesh, N., Zhou, J., & Ozerov, O. V.

citation count

  • 1

complete list of authors

  • Lai, Qingheng||Bhuvanesh, Nattamai||Zhou, Jia||Ozerov, Oleg V

publication date

  • January 2021