Formation of an Ag→Al dative bond is avoided in reactions of an alane/tris(phosphine) ligand with monovalent silver
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An alane/tris(phospine) ligand reacts with AgOTf by coordination of three phosphines to the Ag center and transfer of triflate to the tris(pyrrolyl) Al site. Reaction with Ag[HCB11Cl11] results in the coordination of two phosphines to Ag and one to Al, with no significant Ag-Al bonding in either structure.
author list (cited authors)
Lai, Q., Bhuvanesh, N., Zhou, J., & Ozerov, O. V.
complete list of authors
Lai, Qingheng||Bhuvanesh, Nattamai||Zhou, Jia||Ozerov, Oleg V