Kinetics of the (salen)Cr(iii)- and (salen)Co(iii)-catalyzed copolymerization of epoxides with CO2, and of the accompanying degradation reactions Academic Article uri icon

abstract

  • The catalytic cycle of the (salen)M(iii)-catalyzed copolymerization for a variety of epoxides with CO2is elucidated using computational chemistry, and factors that control the kinetics and product distribution of these reactions are described.

published proceedings

  • Polymer Chemistry

altmetric score

  • 0.5

author list (cited authors)

  • Darensbourg, D. J., & Yeung, A. D.

citation count

  • 30

complete list of authors

  • Darensbourg, DJ||Yeung, AD

publication date

  • January 2015