Radiation-induced phase transformations in MgAl2O4 spinel Academic Article uri icon

abstract

  • Ion-irradiation was observed to transform MgAl2O4 spinel first to a metastable crystalline phase and then to an amorphous phase at cryogenic temperatures. Elastic stiffening of 15% occurred upon formation of the metastable crystalline phase. A second transformation from the metastable crystalline spinel to an amorphous state was accompanied by elastic softening of 25% relative to unirradiated spinel. This phase transformation behavior in spinel appears to be different from that in intermetallic compounds where only elastic softening associated with radiation damage accumulation is observed. A two-stage radiation damage model is proposed to explain the observed phase transformations.

published proceedings

  • Journal of Materials Research

author list (cited authors)

  • Yu, N., Devanathan, R., Sickafus, K. E., & Nastasi, M.

citation count

  • 21

complete list of authors

  • Yu, Ning||Devanathan, Ram||Sickafus, Kurt E||Nastasi, Michael

publication date

  • July 1997