Conformational Switching through the One-Electron Reduction of an Acridinium-based, -Cationic Phosphine Gold Complex. Academic Article uri icon

abstract

  • Our efforts in the chemistry of gold complexes featuring ambiphilic phosphine-carbenium L/Z-type ligand have led us to consider the reduction of the carbenium moiety as a means to modulate the gold-carbenium interaction present in these complexes. Here, it was shown that the one-electron reduction of [(o-Ph2 P(C6 H4 )Acr)AuCl]+ (Acr=9-N-methylacridinium) produces a neutral stable radical, the structure of which showed a marked increase in the Au-Acr distance. Related structural changes were observed for the phosphine oxide analogue [(o-Ph2 P(O)(C6 H4 )Acr]+ , the reduction of which interfered with the P=Ocarbenium interaction. These structural effects, driven by a reduction-induced change in the electronic and electrostatic characteristics of the compounds, showed that the charge and accepting properties of the carbenium unit can be modulated. These results highlight the redox-noninnocence of carbenium Z-type ligand, a feature that can be exploited to induce specific conformational changes.

published proceedings

  • Chemistry

altmetric score

  • 13.6

author list (cited authors)

  • Liu, W., Kim, Y., & Gabbai, F. P.

citation count

  • 6

complete list of authors

  • Liu, Wei-Chun||Kim, Youngmin||Gabbaiï, François P

publication date

  • April 2021

publisher