Unsymmetrical dirhodium single molecule photocatalysts for H2 production with low energy light.
Academic Article
Overview
Identity
Additional Document Info
View All
Overview
abstract
New axially blocked unsymmetrical dirhodium complexes photocatalyze the production of H2 under red light irradiation with a turnover number (TON) of 23 3 in the presence of acid and a sacrificial donor. The presence of multiple metal/ligand-to-ligand charge transfer transitions improves their absorption of light into the near-IR.