Unsymmetrical dirhodium single molecule photocatalysts for H 2 production with low energy light Academic Article uri icon

abstract

  • New axially blocked unsymmetrical dirhodium complexes photocatalyze the production of H2 under red light irradiation with a turnover number (TON) of 23 ± 3 in the presence of acid and a sacrificial donor. The presence of multiple metal/ligand-to-ligand charge transfer transitions improves their absorption of light into the near-IR.

altmetric score

  • 1

author list (cited authors)

  • Millet, A., Xue, C., Turro, C., & Dunbar, K. R.

citation count

  • 0

publication date

  • February 2021