Indirect detection of intermediate in decarboxylation reaction of phenylglyoxylic acid by hyperpolarized 13C NMR. Academic Article

abstract

• The decarboxylation reaction of phenylglyoxylic acid with hydrogen peroxide is studied by real-time hyperpolarized carbon-13 nuclear magnetic resonance (13C NMR) spectroscopy at room temperature. A non-observable reaction intermediate is identified using blind selective saturation pulses in the expected chemical shift range, thereby revealing information on the reaction mechanism.

authors

• Hilty, Christian

published proceedings

• Chem Commun (Camb)

altmetric score

• 1.25

author list (cited authors)

• Kim, J., Kim, Y., Luu, Q. S., Kim, J., Qi, C., Hilty, C., & Lee, Y.

citation count

• 3

complete list of authors

• Kim, Jiwon||Kim, Yaewon||Luu, Quy Son||Kim, Jihyun||Qi, Chang||Hilty, Christian||Lee, Youngbok

publication date

• January 2020

publisher

• Royal Society of Chemistry (RSC)  Publisher

published in

• Chemical Communications  Journal

PubMed Central ID

• 33185204

Digital Object Identifier (DOI)

• 10.1039/d0cc06331b

start page

• 15000

end page

• 15003

volume

• 56

issue

• 95