Super Gas Barrier of a Polyelectrolyte/Clay Coacervate Thin Film. Academic Article uri icon


  • Transparent polymeric thin films with high oxygen barrier are important for extending the shelf life of food and protecting flexible organic electronic devices. Polyelectrolyte/clay multilayer nanocoatings are shown to exhibit super gas barrier performance, but the layer-by-layer assembly process requires numerous deposition steps. In an effort to more quickly fabricate this type of barrier, a polyelectrolyte/clay coacervate composed of branched polyethyleneimine (PEI), poly(acrylic acid) (PAA), and kaolinite (KAO) clay is prepared and deposited in a single step, followed by humidity and thermal post-treatments. When deposited onto a 179 m poly(ethylene terephthalate) (PET) film, a 4 m coacervate coating reduces the oxygen transmission rate (OTR) by more than three orders of magnitude, while maintaining high transparency. This single-step deposition process uses only low-cost, water-based components and ambient conditions, which can be used to for sensitive food and electronics packaging.

published proceedings

  • Macromol Rapid Commun

altmetric score

  • 3

author list (cited authors)

  • Chiang, H., Kolibaba, T. J., Eberle, B., & Grunlan, J. C.

citation count

  • 7

complete list of authors

  • Chiang, Hsu-Cheng||Kolibaba, Thomas J||Eberle, Bailey||Grunlan, Jaime C

publication date

  • February 2021