Ni complexes of an alane/tris(phosphine) ligand built around a strongly Lewis acidic tris(N-pyrrolyl)aluminum.
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Syntheses of a new tripodal alane/tris(phosphine) ligand (AlP3) based on 2-(diisopropylphosphino)pyrrole, and AlP3-supported Ni complexes are reported. The central tris(pyrrolyl)aluminum moiety acts as a stronger Lewis acid towards Ni than other related group 13 element-centered tripodal ligands, as demonstrated by the binding of H2 to Ni and the ease of reduction.
author list (cited authors)
Lai, Q., Cosio, M. N., & Ozerov, O. V.
complete list of authors
Lai, Qingheng||Cosio, Mario N||Ozerov, Oleg V