Minimization of Organocuprate Complexity through Self‐Organization: Remarkable Orientation Effect in Mixed Cuprate π Complexes Academic Article uri icon

abstract

  • They "know" where to go: a powerful orientation effect has been observed in complexes of mixed organocuprates [R(T)R(NT)CuLi] and substrates with C-C, C-N, and C-S double bonds (see scheme; Th=thienyl). The preferred geometry of the intermediate complex sets up the facile addition of R(T) to the double bond, rather than addition of the "dummy ligand", R(NT) .

altmetric score

  • 0.25

author list (cited authors)

  • Bertz, S. H., Hardin, R. A., Murphy, M. D., Ogle, C. A., Richter, J. D., & Thomas, A. A.

citation count

  • 23

publication date

  • March 2012

publisher