Rapid Injection NMR Reveals η3 ‘π-Allyl’ CuIII Intermediates in Addition Reactions of Organocuprate Reagents
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By using rapid injection NMR, it has now been possible to prepare and characterize the η(3) 'π-allyl' copper(III) intermediate that has been proposed for addition reactions of organocopper(I) reagents and α,β-unsaturated carbonyl compounds.
author list (cited authors)
Bertz, S. H., Hardin, R. A., Murphy, M. D., Ogle, C. A., Richter, J. D., & Thomas, A. A.