Hydrothermal synthesis and crystal structure of (H3NCH2CH2NH3)[V(OH)(HPO4)(2)].H2O with novel 1-D {v(3+)-OH-v(3+)} polymeric chains Academic Article uri icon


  • A new VIII vanadium phosphate, (H3NCH2CH2NH3) [V (OH) (HPO4)2] H2O (1) , with a novel 1-D polymeric chain structure was prepared hydrothermally and its structure determined by X-ray diffraction. The structure consists of infinite {V (OH) (HPO4)2} 2- chains, ethylenediammonium dications and lattice water molecules. The {V (OH) (HPO4)2} 2- chains contain an infinite {V3 - OH - V3} backbone bridged by (HPO4) 2- groups. Each V3 atom has a quite regular octahedral configuration containing four phosphate oxygens and two trans positioned OH groups.

published proceedings


author list (cited authors)

  • Zhang, Y. P., Warren, C. J., Clearfield, A., & Haushalter, R. C.

citation count

  • 16

complete list of authors

  • Zhang, YP||Warren, CJ||Clearfield, A||Haushalter, RC

publication date

  • July 1998