Hydrothermal synthesis and crystal structure of (H3NCH2CH2NH3)[V(OH)(HPO4)(2)].H2O with novel 1-D {v(3+)-OH-v(3+)} polymeric chains Academic Article

abstract

• A new VIII vanadium phosphate, (H3NCH2CH2NH3) [V (OH) (HPO4)2] H2O (1) , with a novel 1-D polymeric chain structure was prepared hydrothermally and its structure determined by X-ray diffraction. The structure consists of infinite {V (OH) (HPO4)2} 2- chains, ethylenediammonium dications and lattice water molecules. The {V (OH) (HPO4)2} 2- chains contain an infinite {V3 - OH - V3} backbone bridged by (HPO4) 2- groups. Each V3 atom has a quite regular octahedral configuration containing four phosphate oxygens and two trans positioned OH groups.

authors

• Clearfield, Abraham

published proceedings

• POLYHEDRON

author list (cited authors)

• Zhang, Y. P., Warren, C. J., Clearfield, A., & Haushalter, R. C.

citation count

• 16

complete list of authors

• Zhang, YP||Warren, CJ||Clearfield, A||Haushalter, RC

publication date

• July 1998

publisher

• Elsevier  Publisher

published in

• Polyhedron  Journal

keywords

• Hydrothermal Synthesis
• Vanadium Phosphates
• X-ray Crystal Structure

Digital Object Identifier (DOI)

• 10.1016/S0277-5387(97)90188-1

start page

• 2575

end page

• 2580

volume

• 17

issue

• 15

URL

• http://dx.doi.org/10.1016/s0277-5387(97)90188-1