Magnetostructural and EPR Studies of Anisotropic Vanadium trans-Dicyanide Molecules. Academic Article

abstract

• A series of trans-dicyanide vanadium(III) compounds based on acetylacetonate, (PPN)[VIII(acac)2(CN)2](PPN)Cl2MeCN (1), and salen ligands, (Et4N)[VIII(salen)(CN)2] (2a), (PPN)[VIII(MeOsalen)(CN)2]DMF2MeCN (3), and (PPN)[VIII(salphen)(CN)2]DMF (4) [salen = N,N'-ethylenebis(salicyl-imine), MeOsalen = N,N'-ethylenebis(methoxysalicylimine), salphen = N,N'-phenylenebis(salicyl-imine), and PPN = bis(triphenylphosphine)iminium], were prepared and structurally characterized. High-field EPR studies reveal that the complexes exhibit moderate magnetic anisotropy with positive D values of +5.70, +3.80, +4.05, and +3.99 cm-1 for 1-4, respectively.

authors

• Dunbar, Kim

published proceedings

• Inorg Chem

author list (cited authors)

• Saber, M. R., Thirunavukkuarasu, K., Greer, S. M., Hill, S., & Dunbar, K. R.

citation count

• 5

complete list of authors

• Saber, Mohamed R||Thirunavukkuarasu, Komalavalli||Greer, Samuel M||Hill, Stephen||Dunbar, Kim R

publication date

• September 2020

publisher

• American Chemical Society (ACS)  Publisher

published in

• Inorganic Chemistry  Journal

PubMed Central ID

• 32869626

Digital Object Identifier (DOI)

• 10.1021/acs.inorgchem.0c01595

start page

• 13262

end page

• 13269

volume

• 59

issue

• 18

URL

• http://dx.doi.org/10.1021/acs.inorgchem.0c01595