Atomic Hourglass and Thermometer Based on Diffusion of a Mobile Dopant in VO2. Academic Article uri icon

abstract

  • Transformations between different atomic configurations of a material oftentimes bring about dramatic changes in functional properties as a result of the simultaneous alteration of both atomistic and electronic structure. Transformation barriers between polytypes can be tuned through compositional modification, generally in an immutable manner. Continuous, stimulus-driven modulation of phase stabilities remains a significant challenge. Utilizing the metal-insulator transition of VO2, we exemplify that mobile dopants weakly coupled to the crystal lattice provide a means of imbuing a reversible and dynamical modulation of the phase transformation. Remarkably, we observe a time- and temperature-dependent evolution of the relative phase stabilities of the M1 and R phases of VO2 in an "hourglass" fashion through the relaxation of interstitial boron species, corresponding to a 50 °C modulation of the transition temperature achieved within the same compound. The material functions as both a chronometer and a thermometer and is "reset" by the phase transition. Materials possessing memory of thermal history hold promise for applications such as neuromorphic computing, atomic clocks, thermometry, and sensing.

published proceedings

  • J Am Chem Soc

altmetric score

  • 58.61

author list (cited authors)

  • Sellers, D. G., Braham, E. J., Villarreal, R., Zhang, B., Parija, A., Brown, T. D., ... Banerjee, S.

citation count

  • 10

complete list of authors

  • Sellers, Diane G||Braham, Erick J||Villarreal, Ruben||Zhang, Baiyu||Parija, Abhishek||Brown, Timothy D||Alivio, Theodore EG||Clarke, Heidi||De Jesus, Luis R||Zuin, Lucia||Prendergast, David||Qian, Xiaofeng||Arroyave, Raymundo||Shamberger, Patrick J||Banerjee, Sarbajit

publication date

  • September 2020