Multielectron C-H photoactivation with an Sb(v) oxo corrole.
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Pnictogen complexes are ideal for mediating multi-electron chemical reactions in two-electron steps. We report an Sb(v) bis--oxo corrole that photochemically oxidises the C-H bonds of organic substrates. In the case of toluene, the substrate is oxidised to benzaldehyde, a rare example of a four-electron photoreaction.
author list (cited authors)
Lemon, C. M., Maher, A. G., Mazzotti, A. R., Powers, D. C., Gonzalez, M. I., & Nocera, D. G