Addition of ammonia, water, and dihydrogen across a single Pd-Pd bond. Academic Article

abstract

• Pincer-supported Pd alkyl complexes (PNP)PdR undergo photochemical conversion to a dimeric (PNP)Pd-Pd(PNP) complex with a single Pd-Pd bond. Dissociation of the dimer into monomeric (PNP)Pd species is kinetically accessible thermally and photochemically. (PNP)Pd-Pd(PNP) reacts with ammonia, water, and dihydrogen by adding the H-X bond of the substrate (X = NH2, OH, H) across the Pd-Pd bond. For ammonia, this represents a rare example of conversion of NH3 to terminal hydride and amide ligands by a bimetallic complex. Copyright 2007 American Chemical Society.

authors

• Ozerov, Oleg

published proceedings

• J Am Chem Soc

author list (cited authors)

• Fafard, C. M., Adhikari, D., Foxman, B. M., Mindiola, D. J., & Ozerov, O. V.

citation count

• 169

complete list of authors

• Fafard, Claudia M||Adhikari, Debashis||Foxman, Bruce M||Mindiola, Daniel J||Ozerov, Oleg V

publication date

• August 2007

publisher

• American Chemical Society (ACS)  Publisher

published in

• Journal of the American Chemical Society  Journal

keywords

• Brain Disorders
• Neurodegenerative

PubMed Central ID

• 17685527

Digital Object Identifier (DOI)

• 10.1021/ja0731571

start page

• 10318

end page

• 10319

volume

• 129

issue

• 34

URL

• http://dx.doi.org/10.1021/ja0731571