Silver(I) and thallium(I) complexes of a PNP ligand and their utility as PNP transfer reagents.

abstract

• Silver(I) and thallium(I) complexes of a diarylamido-based PNP pincer ligand have been prepared and characterized. The silver complex [(PNP)Ag]2 exists as a dimer both in solution and in the solid state and is stable under an ambient atmosphere. Thallium complex (PNP)Tl is, however, monomeric and acutely sensitive to moisture and air. Both reagents serve to transfer PNP into the coordination sphere of divalent nickel, palladium, and platinum. [(PNP)Ag]2 is able to effect PNP transfer in air, but the transfer to nickel(II) is less efficient than that with the thallium(I) analogue.

authors

• Ozerov, Oleg

published proceedings

• Inorg Chem

author list (cited authors)

• DeMott, J. C., Basuli, F., Kilgore, U. J., Foxman, B. M., Huffman, J. C., Ozerov, O. V., & Mindiola, D. J.

citation count

• 35

complete list of authors

• DeMott, Jessica C||Basuli, Falguni||Kilgore, Uriah J||Foxman, Bruce M||Huffman, John C||Ozerov, Oleg V||Mindiola, Daniel J

publication date

• August 2007

publisher

• American Chemical Society (ACS)  Publisher

published in

• Inorganic Chemistry  Journal

keywords

• Chemistry
• Crystallography, X-Ray
• Ligands
• Magnesium
• Metals
• Models, Chemical
• Models, Molecular
• Molecular Conformation
• Probability
• Purine-nucleoside Phosphorylase
• Silver
• Thallium

PubMed Central ID

• 17616122

Digital Object Identifier (DOI)

• 10.1021/ic0700598

start page

• 6271

end page

• 6276

volume

• 46

issue

• 16

URL

• http://dx.doi.org/10.1021/ic0700598