Early-late heterobimetallic Rh-Ti and Rh-Zr complexes via addition of early metal chlorides to mono- and divalent rhodium. Academic Article

abstract

• Addition of TiCl(4) or ZrCl(4) to (PNP)Rh(CH(2)==CH(t)Bu) (1) rapidly gives complexes (PNP)Rh(MCl(3))(Cl) (M = Ti, 2; Zr, 3) in 75-77% yield (PNP = (4-Me-2-((i)Pr(2)P)-C(6)H(3))(2)N). Compound 2 can also be synthesized via a reaction of (PNP)RhCl with TiCl(3) or of (PNP)TiCl(3) with 1/2 [(cod)RhCl](2).

authors

• Ozerov, Oleg

published proceedings

• Chem Commun (Camb)

author list (cited authors)

• Smith, D. A., & Ozerov, O. V.

citation count

• 12

complete list of authors

• Smith, Dan A||Ozerov, Oleg V

publication date

• October 2011

publisher

• Royal Society of Chemistry (RSC)  Publisher

published in

• Chemical Communications  Journal

keywords

• 0302 Inorganic Chemistry

PubMed Central ID

• 21892470

Digital Object Identifier (DOI)

• 10.1039/c1cc14373e

start page

• 10779

end page

• 10781

volume

• 47

issue

• 38

URL

• http://dx.doi.org/10.1039/c1cc14373e