Magnetic properties of complex d(1) and d(5) ions: crystal field model and Jahn-Teller effect Conference Paper

abstract

• In this paper, the low lying levels of d1 and low-spin d5 metal complexes possessing ground 2T2 term are considered. Strong spin-orbital interactions is taken into account along with the axial (trigonal or tetragonal) component of the crystal field. In the framework of the semi-classic adiabatic approximation, vibronic Jahn-Teller and pseudo Jahn -Teller interactions acting within the ground manifold are also considered. The influence of the low-symmetry crystal fields, covalence reduction factor, spin-orbital and Jahn-Teller interactions on the anisotropy of g-factors, temperature independent paramagnetic contributions, and magnetic susceptibility is elucidated. 2003 Elsevier Science Ltd. All rights reserved.

authors

• Dunbar, Kim

published proceedings

• POLYHEDRON

author list (cited authors)

• Dunbar, K. R., Schelter, E. J., Tsukerblat, B. S., Ostrovsky, S. M., Mirovitsky, V. Y., & Palii, A. V.

citation count

• 10

complete list of authors

• Dunbar, KR||Schelter, EJ||Tsukerblat, BS||Ostrovsky, SM||Mirovitsky, VY||Palii, AV

publication date

• July 2003

publisher

• Elsevier  Publisher

published in

• Polyhedron  Journal

keywords

• D(1)and D(5) Metal Complexes
• Jahn-teller Effect
• Magnetic Properties

Digital Object Identifier (DOI)

• 10.1016/S0277-5387(03)00294-8

start page

• 2545

end page

• 2556

volume

• 22

issue

• 14-17

URL

• http://dx.doi.org/10.1016/s0277-5387(03)00294-8