HAT(CN)(6): a new building block for molecule-based magnetic materials
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abstract
The ability of reduced forms of HAT(CN)6 to be used as ligands to construct novel magnetic materials is reported and discussed herein. Binary compounds of first row transition metals with discrete or extended polymeric structures are presented. All compounds exhibit characteristic paramagnetic behaviour except for a polymeric {Cu-HAT(CN)6} phase that behaves as a canted antiferromagnet below 6 K. 2001 Elsevier Science B.V.