A series of stable salts of the oxidized donors TTF, o-Me2TTF, TMTTF, and TTF(SCH2CH2CN)(4) Academic Article

abstract

• Reactions of the organic donors tetrathiafulvalene (TTF), o-dimethyltetrathiafulvalene (o-Me2TTF), tetramethyltetrathiafulvalene (TMTTF), and tetrathiafulvalene tetrathiolate [TTF(SCH2CH2CN)4] with oxidizing agents of suitable potential resulted in the formation of stable salts in which the donors are present in their monocationic radical forms. The salts presented herein represent a series of reagents containing oxidized chalcofulvalene donors that can be used as starting materials for metathesis reactions with other cations. All of the salts were characterized by X-ray crystallography and UV-vis-NIR spectroscopy. 2008 Elsevier B.V. All rights reserved.

authors

• Dunbar, Kim

published proceedings

• SYNTHETIC METALS

author list (cited authors)

• Reinheimer, E. W., Zhao, H., & Dunbar, K. R.

citation count

• 20

complete list of authors

• Reinheimer, Eric W||Zhao, Hanhua||Dunbar, Kim R

publication date

• July 2008

publisher

• Elsevier  Publisher

published in

• Synthetic Metals  Journal

keywords

• Cations
• Organic Donors
• Stable Salts

Digital Object Identifier (DOI)

• 10.1016/j.synthmet.2008.03.008

start page

• 447

end page

• 452

volume

• 158

issue

• 11

URL

• http://dx.doi.org/10.1016/j.synthmet.2008.03.008