Hydrogen Bonding and Sulfur-Sulfur Interactions in the Crystal Structure of the Radical-Cation Salt (BPDT-TTF)(2)[W6O19]
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abstract
The synthesis and crystal structure of the salt (BPDT-TTF) 2[W6O19] is described. The compound crystallizes in the triclinic space group P - 1 with a = 10.927(2) , b = 11.904(2) , c = 12.660(2) , = 101.261(5), = 115.174(5), and = 114.434(5). The bond length of the central C=C bond in BPDT-TTF is 1.384(17) , in accord with an oxidation state of +1 for the BPDT-TTF radical-cations and the observed stoichiometry between BPDT-TTF and [W6O19]2- which is 2:1. 2009 Springer Science+Business Media, LLC.