Synthesis, structure and magnetic properties of the one-dimensional chain compound {K[Fe(1,3,5-triazine-2,4,6-tricarboxylate)(H 2 O) 2 ]·2H 2 O} ∞ Academic Article uri icon

abstract

  • The one-dimensional chain compound {[Fe(1,3,5-triazine-2,4,6-tricarboxylate)(H2O)2]} nn- was obtained from a reaction of 1,3,5-triazine-2,4,6-tricarboxylate with Fe(II) in water at room temperature. The high-spin Fe(II) centers adopt a pentagonal bipyramid geometry with unusual ligand binding modes. Magnetic measurements revealed weak magnetic interactions between paramagnetic centers; these were modeled with both axial and rhombic distortions.

author list (cited authors)

  • Galán-Mascarós, J., Clemente-Juan, J., & Dunbar, K. R.

citation count

  • 23

publication date

  • May 2002