A new family of dimolybdenum compounds with cyanide and phosphine ligands
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abstract
Reaction of Mo2Cl4(dppm)2 with excess [n-Bu4N] [CN] produces [Bu4N]2[Mo2(II,II)(CN)6(dppm)2]2(CH3CN) 2(C6H6) (1) the first example of an edge-sharing bioctahedral compound of Mo(II), that upon exposure to air oxidizes to the mixed valence analog [Bu4N] [Mo2(II,III)(CN)6(dppm)2]2(H2O) 2(CH3CN) (2). (C) 2000 Elsevier Science S.A.