A new family of dimolybdenum compounds with cyanide and phosphine ligands Academic Article uri icon

abstract

  • Reaction of Mo2Cl4(dppm)2 with excess [n-Bu4N] [CN] produces [Bu4N]2[Mo2(II,II)(CN)6(dppm)2]2(CH3CN) 2(C6H6) (1) the first example of an edge-sharing bioctahedral compound of Mo(II), that upon exposure to air oxidizes to the mixed valence analog [Bu4N] [Mo2(II,III)(CN)6(dppm)2]2(H2O) 2(CH3CN) (2). (C) 2000 Elsevier Science S.A.

published proceedings

  • INORGANIC CHEMISTRY COMMUNICATIONS

author list (cited authors)

  • Szalay, P. S., & Dunbar, K. R.

citation count

  • 16

complete list of authors

  • Szalay, PS||Dunbar, KR

publication date

  • February 2000