Radical salts of TTF derivatives with the metal-metal bonded [Re2Cl8](2-) anion Academic Article

abstract

• Four new salts of the radical cations of TMTSF (tetramethyltetraselenafulvalene), TMTTF (tetramethyltetrathiafulvalene), BEDT-TTF (bisethylenedithiotetrathia-fulvalene) (ET) and o-Me2TTF (o-4,4-dimethyltetrathiafulvalene) with the metal-metal bonded dianion [Re2Cl8]2- were synthesized, and their structures and physical properties investigated. The structures of these semiconducting salts feature one-dimensional stacking of the donor molecules interleaved with [Re2Cl8]2- anions and interstitial solvent molecules. 2008 Elsevier B.V. All rights reserved.

authors

• Dunbar, Kim

published proceedings

• JOURNAL OF MOLECULAR STRUCTURE

author list (cited authors)

• Reinheimer, E. W., Galan-Mascaros, J. R., Gomez-Garcia, C. J., Zhao, H., Fourmigue, M., & Dunbar, K. R.

citation count

• 14

complete list of authors

• Reinheimer, Eric W||Galán-Mascarós, José R||Gómez-García, Carlos J||Zhao, Hanhua||Fourmigué, Marc||Dunbar, Kim R

publication date

• November 2008

publisher

• Elsevier  Publisher

published in

• JOURNAL OF MOLECULAR STRUCTURE  Journal

keywords

• Bedt-ttf
• O-me2ttf
• Octachlorodirhenate
• Tmtsf
• Tmttf
• Ttf

Digital Object Identifier (DOI)

• 10.1016/j.molstruc.2008.03.046

start page

• 81

end page

• 89

volume

• 890

issue

• 1-3

URL

• http://dx.doi.org/10.1016/j.molstruc.2008.03.046