Magnetic properties of a low symmetry d(5) complex: An adiabatic Pseudo-Jahn-Teller problem Conference Paper

abstract

• A vibronic model for the magnetic properties of a low-spin d5 metal complex is reported. The splitting of the ground 2T2-term by the strong spin-orbital interaction and the trigonal component of the crystal field as well as the covalency effects are taken into account. The pseudo-Jahn-Teller mixing of the low-lying states is also considered in the framework of the semiclassic adiabatic approximation. The influence of the named interactions on the g-tensor and on the tensor of the temperature-independent paramagnetism is elucidated. 2003 Elsevier Inc. All rights reserved.

authors

• Dunbar, Kim

published proceedings

• ADVANCES IN QUANTUM CHEMISTRY, VOL 44

author list (cited authors)

• Dunbar, K. R., Schelter, E. J., Tsukerblat, B. S., Palii, A. V., Ostrovsky, S. M., Mirovitskii, V. Y., & Klokishner, S. I.

citation count

• 2

complete list of authors

• Dunbar, KR||Schelter, EJ||Tsukerblat, BS||Palii, AV||Ostrovsky, SM||Mirovitskii, VY||Klokishner, SI

publication date

• December 2003

publisher

• Elsevier  Publisher

published in

• Advances in Quantum Chemistry  Journal

keywords

• 34 Chemical Sciences
• 3402 Inorganic Chemistry

Digital Object Identifier (DOI)

• 10.1016/S0065-3276(03)44027-6

International Standard Book Number (ISBN) 10

• 0-12-034844-6

International Standard Book Number (ISBN) 13

• 9780120348442

start page

• 413

end page

• 428

volume

• 44

URL

• http://dx.doi.org/10.1016/s0065-3276(03)44027-6