The first crystal structure of a one-dimensional chain of linked Ru-II=Ru-II units Academic Article

abstract

• The one-dimensional polymer [Ru2(O2CCF 3)4(Phz) 1 (Phz = phenazine) was synthesized by the reaction of RuII2(O2CCF 3)4(THF)2 with phenazine. An X-ray crystallographic analysis revealed that the compound consists of Ru 2(O2CCF3)4 units bridged by phenazine ligands. The Ru-Ru bond distance is 2.3109(10) and the axial Ru-N distance is 2.425(2) . Magnetic measurements performed in the temperature range 1.8.300 K indicate that the S = 1 RuII2 units are weakly antiferromagnetically coupled (zJ = -3.0 cm-1) with a large zero-field splitting (D = 277 cm-1). The Royal Society of Chemistry 2001.

authors

• Dunbar, Kim

published proceedings

• JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS

author list (cited authors)

• Miyasaka, H., Clerac, R., Campos-Fernandez, C. S., & Dunbar, K. R.

citation count

• 66

complete list of authors

• Miyasaka, H||Clerac, R||Campos-Fernandez, CS||Dunbar, KR

publication date

• December 2001

publisher

• Royal Society of Chemistry (RSC)  Publisher

published in

• n1472-7773ISSN  Journal

keywords

• Diruthenium
• Magnetic Properties
• Paramagnetism
• Polymer
• Transition Metals

Digital Object Identifier (DOI)

• 10.1039/b007079n

start page

• 858

end page

• 861

volume

• 0

issue

• 6

URL

• http://dx.doi.org/10.1039/b007079n