STEREOSPECIFIC INTRODUCTION OF CARBON-MONOXIDE INTO METAL-CARBONYL CHELATE COMPLEXES

abstract

• The chelate complex, Mo(CO)4[(C6H5)2PCH2CH2CH2N(CH3)2], reacts with 13CO in solution with replacement of the N-donor end of the ligand giving cis- Mo(CO)4(13CO)[(C6H5)2PCH2CH2CH2N(CH3)2] in which the 13CO coordinates stereospecifically cis to the P atom; similarly the tridentate chelate complex, cis-Mo(CO)3[(C6H5)2PCH2CH2N(C2H5)CH2CH2P(C6H5)2], reacts with 13CO to yield the N-displaced product in which the two P atoms remain coordinated cis to each other and the 13CO coordinates cis to both P atoms. These remarkable stereospecific reactions with CO are discussed in terms of structures of possible reactive intermediates. 1974.

authors

• Darensbourg, Donald

published proceedings

• JOURNAL OF ORGANOMETALLIC CHEMISTRY

author list (cited authors)

• KNEBEL, W. J., GANSOW, O. A., & DARENSBOURG, D. J.

citation count

• 19

complete list of authors

• KNEBEL, WJ||GANSOW, OA||DARENSBOURG, DJ

publication date

• February 1974

publisher

• Elsevier  Publisher

published in

• Journal of Organometallic Chemistry  Journal

keywords

• 34 Chemical Sciences
• 3402 Inorganic Chemistry

Digital Object Identifier (DOI)

• 10.1016/S0022-328X(00)93872-5

start page

• C11

end page

• C13

volume

• 66

issue

• 1

URL

• http://dx.doi.org/10.1016/s0022-328x(00)93872-5