SYNTHESIS AND SPECTRAL PROPERTIES OF MANGANESE PENTACARBONYL PHOSPHINE AND PHOSPHITE CATION DERIVATIVES AND RELATED COMPLEXES
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abstract
The preparations of a variety of monosubstituted manganese carbonyl cationic species of the form [Mn(CO)5L][PF6] are reported. Infraredspectral (including C-K force constant calculations) and reactivity properties of these derivatives are discussed as well. 1974.