The synthesis and spectral properties of manganese pentacarbonyl phosphine and phosphite cation derivatives and related complexes
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abstract
The preparations of a variety of monosubstituted manganese carbonyl cationic species of the form [Mn(CO)5L][PF6] are reported. Infraredspectral (including C-K force constant calculations) and reactivity properties of these derivatives are discussed as well. 1974.