STEREOSPECIFIC INCORPORATION OF CO-13 INTO OLEFINIC SUBSTITUTED METAL-CARBONYL COMPOUNDS

abstract

• The triene complex, (bicyclo[6.1.0] nona-2,4,6-triene)molybdenum tricarbonyl, has been observed to react with 13CO in solution to afford stereospecifically the axially labelled 13CO tetracarbonyl derivative. Further reactions of this 13CO derivative with triphenylphosphine or bis(1,2-diphenylphosphino)ethane resulted in formation of the cis disubstituted phosphine derivatives with retention of the 13CO label. 1976.

authors

• Darensbourg, Donald

published proceedings

• JOURNAL OF ORGANOMETALLIC CHEMISTRY

author list (cited authors)

• DARENSBOURG, D. J., & SALZER, A.

citation count

• 5

complete list of authors

• DARENSBOURG, DJ||SALZER, A

publication date

• September 1976

publisher

• Elsevier  Publisher

published in

• Journal of Organometallic Chemistry  Journal

keywords

• 34 Chemical Sciences
• 3402 Inorganic Chemistry
• 3405 Organic Chemistry

Digital Object Identifier (DOI)

• 10.1016/S0022-328X(00)87219-8

start page

• C90

end page

• C92

volume

• 117

issue

• 4

URL

• http://dx.doi.org/10.1016/s0022-328x(00)87219-8