Stereospecific incorporation of 13CO into olefinic substituted metal carbonyl compounds Academic Article uri icon

abstract

  • The triene complex, (bicyclo[6.1.0] nona-2,4,6-triene)molybdenum tricarbonyl, has been observed to react with 13CO in solution to afford stereospecifically the axially labelled 13CO tetracarbonyl derivative. Further reactions of this 13CO derivative with triphenylphosphine or bis(1,2-diphenylphosphino)ethane resulted in formation of the cis disubstituted phosphine derivatives with retention of the 13CO label. © 1976.

author list (cited authors)

  • Darensbourg, D. J., & Salzer, A.

citation count

  • 5

publication date

  • September 1976