Stereospecific incorporation of 13CO into olefinic substituted metal carbonyl compounds Academic Article

abstract

• The triene complex, (bicyclo[6.1.0] nona-2,4,6-triene)molybdenum tricarbonyl, has been observed to react with 13CO in solution to afford stereospecifically the axially labelled 13CO tetracarbonyl derivative. Further reactions of this 13CO derivative with triphenylphosphine or bis(1,2-diphenylphosphino)ethane resulted in formation of the cis disubstituted phosphine derivatives with retention of the 13CO label. © 1976.

authors

• Darensbourg, Donald

author list (cited authors)

• Darensbourg, D. J., & Salzer, A.

citation count

• 5

publication date

• September 1976

publisher

• Elsevier BV  Publisher

published in

• Journal of Organometallic Chemistry  Journal

Digital Object Identifier (DOI)

• 10.1016/s0022-328x(00)87219-8

start page

• c90

end page

• c92

volume

• 117

issue

• 4