LACK OF INTRAMOLECULAR CARBONYL LIGAND REARRANGEMENT IN STEREOSPECIFICALLY CO-13 LABELED (DIAMINE) MOLYBDENUM TETRACARBONYL DERIVATIVES
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abstract
The preparation and spectral characterization of stereospecifically, axially labelled Mo(CO)3(13CO)(diamine) complexes (diamine N,N,N,N-tetramethylethylenediamine and N,N,N,N-tetramethyl-1,3-diaminopropane) and the rigidity (or lack of fluxionality) of the carbonyl ligands during subsequent thermal reactions of these derivatives are reported. 1977.