The lack of intramolecular carbonyl ligand rearrangement in the stereospecifically 13co labelled (diamine)molybdenum tetracarbonyl derivatives Academic Article uri icon

abstract

  • The preparation and spectral characterization of stereospecifically, axially labelled Mo(CO)3(13CO)(diamine) complexes (diamine N,N,N′,N′-tetramethylethylenediamine and N,N,N′,N′-tetramethyl-1,3-diaminopropane) and the rigidity (or lack of fluxionality) of the carbonyl ligands during subsequent thermal reactions of these derivatives are reported. © 1977.

author list (cited authors)

  • Darensbourg, D. J., Todd, L. J., & Hickey, J. P.

citation count

  • 6

publication date

  • September 1977