LACK OF INTRAMOLECULAR CARBONYL LIGAND REARRANGEMENT IN STEREOSPECIFICALLY CO-13 LABELED (DIAMINE) MOLYBDENUM TETRACARBONYL DERIVATIVES uri icon

abstract

  • The preparation and spectral characterization of stereospecifically, axially labelled Mo(CO)3(13CO)(diamine) complexes (diamine N,N,N,N-tetramethylethylenediamine and N,N,N,N-tetramethyl-1,3-diaminopropane) and the rigidity (or lack of fluxionality) of the carbonyl ligands during subsequent thermal reactions of these derivatives are reported. 1977.

published proceedings

  • JOURNAL OF ORGANOMETALLIC CHEMISTRY

author list (cited authors)

  • DARENSBOURG, D. J., TODD, L. J., & HICKEY, J. P.

citation count

  • 6

complete list of authors

  • DARENSBOURG, DJ||TODD, LJ||HICKEY, JP

publication date

  • September 1977