A thermal route to stereospecifically 13CO labelled group VIB metal pentacarbonyl amine derivatives
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A method for the synthesis of stereospecifically, equatorially labelled cis-M(CO)4(13CO)(amine) derivatives where M = Cr, Mo, and W has been developed involves 13CO substitution into the vacant coordination site created by the facile dissociation of an amine ligand from cis-M(CO)4(amine)2 derivatives. The mechanistic implications of this extremely stereoselective reaction are discussed. © 1977.
author list (cited authors)
Darensbourg, D. J., & Kump, R. L.