THERMAL ROUTE TO STEREOSPECIFICALLY (CO)-C-13 LABELED GROUP VIB METAL PENTACARBONYL AMINE DERIVATIVES uri icon

abstract

  • A method for the synthesis of stereospecifically, equatorially labelled cis-M(CO)4(13CO)(amine) derivatives where M = Cr, Mo, and W has been developed involves 13CO substitution into the vacant coordination site created by the facile dissociation of an amine ligand from cis-M(CO)4(amine)2 derivatives. The mechanistic implications of this extremely stereoselective reaction are discussed. 1977.

published proceedings

  • JOURNAL OF ORGANOMETALLIC CHEMISTRY

author list (cited authors)

  • DARENSBOURG, D. J., & KUMP, R. L.

citation count

  • 3

complete list of authors

  • DARENSBOURG, DJ||KUMP, RL

publication date

  • November 1977