JM-PHOS Ligands: Second-Generation Phosphine Oxazolines for Asymmetric Catalysis
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(formula presented) A small library of phosphine oxazollne ligands 2 was prepared and tested in palladium-mediated allylation processes (reactions 1 and 2). They were found to be superior to the first-generation ligands 1 and as effective as the well-known phosphine oxazolines 3.
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