A modular approach to trans-chelating, N-heterocyclic carbene ligand complexes Academic Article

abstract

• The N-methyl bis-imidazolium salts 3 were converted to the silver carbenes 7, then reacted to give palladium(II) complexes 4 with trans-chelating, bidentate bis-imidazolylidine ligands. The similar salts 8, that do not have N-methyl substituents, gave the tetradentate complexes 9 in direct reactions with palladium chloride. The potential of these complexes for asymmetric catalysis is discussed. 2002 Published by Elsevier Science Ltd.

authors

• Burgess, Kevin

published proceedings

• TETRAHEDRON-ASYMMETRY

author list (cited authors)

• Perry, M. C., Cui, X. H., & Burgess, K.

citation count

• 86

complete list of authors

• Perry, MC||Cui, XH||Burgess, K

publication date

• September 2002

publisher

• Elsevier  Publisher

keywords

• 34 Chemical Sciences
• 3402 Inorganic Chemistry

Digital Object Identifier (DOI)

• 10.1016/S0957-4166(02)00535-9

start page

• 1969

end page

• 1972

volume

• 13

issue

• 18

URL

• http://dx.doi.org/10.1016/s0957-4166(02)00535-9