An asymmetric synthesis of D-1,6-Diepicastanospermine Academic Article uri icon

abstract

  • D-1,6-Diepicastanospermine has been prepared via reaction of an allylstannane with the arabinose derivative 1a. This reaction was almost 100 % stereoselective, but the corresponding allylations of aldehydes 1b-d gave mixtures of isomers. Variable stereodifferentiation in these reactions can be attributed to the influence of the distal (γ) chiral center. © 1992.

author list (cited authors)

  • Burgess, K., & Chaplin, D. A.

citation count

  • 21

publication date

  • October 1992