AN ASYMMETRIC-SYNTHESIS OF D-1,6-DIEPICASTANOSPERMINE Academic Article uri icon

abstract

  • D-1,6-Diepicastanospermine has been prepared via reaction of an allylstannane with the arabinose derivative 1a. This reaction was almost 100 % stereoselective, but the corresponding allylations of aldehydes 1b-d gave mixtures of isomers. Variable stereodifferentiation in these reactions can be attributed to the influence of the distal () chiral center. 1992.

published proceedings

  • TETRAHEDRON LETTERS

author list (cited authors)

  • BURGESS, K., & CHAPLIN, D. A.

citation count

  • 24

complete list of authors

  • BURGESS, K||CHAPLIN, DA

publication date

  • October 1992