AN ASYMMETRIC-SYNTHESIS OF D-1,6-DIEPICASTANOSPERMINE Academic Article

abstract

• D-1,6-Diepicastanospermine has been prepared via reaction of an allylstannane with the arabinose derivative 1a. This reaction was almost 100 % stereoselective, but the corresponding allylations of aldehydes 1b-d gave mixtures of isomers. Variable stereodifferentiation in these reactions can be attributed to the influence of the distal () chiral center. 1992.

authors

• Burgess, Kevin

published proceedings

• TETRAHEDRON LETTERS

author list (cited authors)

• BURGESS, K., & CHAPLIN, D. A.

citation count

• 23

complete list of authors

• BURGESS, K||CHAPLIN, DA

publication date

• October 1992

publisher

• Elsevier  Publisher

keywords

• 1,6,7,8-tetrahydroxyindolizidine
• Castanospermine
• Glucosidase Inhibitor

Digital Object Identifier (DOI)

• 10.1016/S0040-4039(00)60010-2

start page

• 6077

end page

• 6080

volume

• 33

issue

• 41

URL

• http://dx.doi.org/10.1016/s0040-4039(00)60010-2