Synthesis and crystal structure of [H2B(3-Phpz)(2)](2)Zn Academic Article

abstract

• Our attempts to synthesize [H2B(3-Phpz)2]Zn(acetate) from K[H2B(3-Phpz)2] and anhydrous zinc acetate has instead resulted in the formation of the 2:1 complex, [H2B(3-Phpz)2]2Zn. This derivative was isolated and crystallized from THF at -10C. Its structure has been defined as a distorted tetrahedron with an average Zn-N bond distance of 2.011(1) as revealed by X-ray crystallography. As anticipated, this complex is inactive at catalyzing the coupling of cyclohexene oxide and carbon dioxide. 2000 Elsevier Science B.V.

authors

• Darensbourg, Donald

published proceedings

• JOURNAL OF ORGANOMETALLIC CHEMISTRY

author list (cited authors)

• Darensbourg, D. J., & Yarbrough, J. C.

citation count

• 3

publication date

• December 2000

publisher

• Elsevier  Publisher

keywords

• Bis-(3-phenylpyrazolyl)dihydroborate
• X-ray Structure
• Zinc

Digital Object Identifier (DOI)

• 10.1016/S0022-328X(00)00594-5

start page

• 305

end page

• 308

volume

• 614

URL

• http://dx.doi.org/10.1016/s0022-328x(00)00594-5