Synthesis and structures of (dialkylamino)ethylcyclopentadienyl derivatives of zinc

abstract

• Lithium salts of (dialkylamino)ethylcyclopentadienyl react with either ZnCl2 or Zn(OAc)2 to afford dimeric derivatives containing bridging chlorides or acetates, respectively. X-ray structural determinations of three such derivatives show that the cyclopentadienyl ligands are bound to the zinc centers in an 1 fashion and via their amine groups, thereby leading to a stable six-membered metallacycle.

authors

• Darensbourg, Donald

published proceedings

• ORGANOMETALLICS

author list (cited authors)

• Darensbourg, D. J., Wildeson, J. R., & Yarbrough, J. C.

citation count

• 28

complete list of authors

• Darensbourg, DJ||Wildeson, JR||Yarbrough, JC

publication date

• October 2001

publisher

• American Chemical Society (ACS)  Publisher

published in

• Organometallics  Journal

keywords

• 34 Chemical Sciences
• 3402 Inorganic Chemistry
• Rare Diseases

Digital Object Identifier (DOI)

• 10.1021/om010519j

start page

• 4413

end page

• 4417

volume

• 20

issue

• 21

URL

• http://dx.doi.org/10.1021/om010519j