Axial Elongation of Mononuclear Lanthanide Metallocenophanes: Magnetic Properties of Dysprosium‐ and Terbium‐[1]Ruthenocenophane Complexes Academic Article uri icon

abstract

  • We report the first f-block-ruthenocenophane complexes 1 (Dy) and 2 (Tb) and provide a comparative discussion of their magnetic structure with respect to earlier reported ferrocenophane analogues. While axial elongation of the rare trigonal-prismatic geometry stabilizes the magnetic ground state in the case of Dy3+ and results in a larger barrier to magnetization reversal (U), a decrease in U is observed for the case of Tb3+ .

altmetric score

  • 3.45

author list (cited authors)

  • Risica, G. M., Vieru, V., Wilkins, B. O., Latendresse, T. P., Reibenspies, J. H., Bhuvanesh, N. S., ... Nippe, M.

citation count

  • 1

complete list of authors

  • Risica, Gabrielle M||Vieru, Veacheslav||Wilkins, Branford O||Latendresse, Trevor P||Reibenspies, Joseph H||Bhuvanesh, Nattamai S||Wylie, Gregory P||Chibotaru, Liviu F||Nippe, Michael

publication date

  • August 2020

publisher