Pyridine-d5 as a 2H NMR probe for investigation of macrostructure and pore shapes in a layered Sn(iv) phosphonate-phosphate material.
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Isotropic and anisotropic motions and molecular states of pyridine-d5, adsorbed on the surface within the pores of a layered Sn(iv) phosphonate-phosphate material (1) have been characterized thermodynamically and kinetically by solid-state NMR. The data obtained provide formulation of macrostructure and shapes of pores in 1.