Mica-Based Multilayer Nanocoating as a Highly Effective Flame Retardant and Smoke Suppressant. Academic Article uri icon


  • Highly flammable polyurethane foam (PUF) remains a key risk factor associated with bedding and upholstered furniture, contributing to the yearly destruction of property and loss of lives. In an attempt to tackle this issue and develop a more benign flame retardant for PUF, a mica-based nanocomposite was deposited using layer-by-layer assembly. Chitosan (CH) and poly(acrylic acid) (PAA) were used to stabilize high-aspect-ratio mica. Foam treated with eight bilayers of CH- and PAA-stabilized mica preserves the porous foam structure, prevents melt dripping, and self-extinguishes during a 10 s torch test, while uncoated foam is completely consumed. When exposed to 35 kW/m2 heat flux during cone calorimetry, the peak heat release rate is reduced by 54% and less-volatile molecules are released during combustion, resulting in a 76% reduction in the total smoke release. This multilayer coating serves as an environmentally benign template for flame-retarding PUF and various other three-dimensional substrates.

published proceedings

  • ACS Appl Mater Interfaces

author list (cited authors)

  • Fahami, A., Lee, J., Lazar, S., & Grunlan, J. C.

citation count

  • 19

complete list of authors

  • Fahami, Abbas||Lee, Jungyu||Lazar, Simone||Grunlan, Jaime C

publication date

  • April 2020