Kinetic Versus Thermodynamic Metalation Enables Synthesis of Isostructural Homo- and Heterometallic Trinuclear Clusters Academic Article uri icon


  • Temperature-dependent metalation of the new hexadentate ligand (tris(5-(pyridin-2-yl)-1H-pyrrol-2-yl)methane; H3TPM) enables the selective synthesis of both mononuclear (i.e. Na(THF)4[Fe(TPM)], kinetic product) and trinuclear (i.e. Fe3(TPM)2, thermodynamic product) complexes. Exposure of Na(THF)4[Fe(TPM)] to FeCl2 or ZnCl2 triggers cluster expansion to generate homo- or heterometallic trinuclear complexes, respectively. The developed approach enables systematic variation of ion content in isostructural metal clusters via programmed assembly.

author list (cited authors)

  • Hyun, S., Upadhyay, A., Das, A., Burns, C., Sung, S., Beaty, J., ... Powers, D.

citation count

  • 0

publication date

  • January 2020