Six-coordinate mononuclear dysprosium(iii) single-molecule magnets with the triphenylphosphine oxide ligand. Academic Article uri icon

abstract

  • Structural, magnetic and theoretical studies of three octahedral mononuclear DyIII complexes with triphenylphosphine oxide and halide ligands are reported. The Cl- and Br- analogues exhibit SMM behavior with energy barriers of 49.1 K and 70.9 K, respectively under a small dc field. Ab initio calculations were performed, the results of which predict higher energy barriers for iodide containing SMMs.

published proceedings

  • Dalton Trans

altmetric score

  • 0.75

author list (cited authors)

  • Vignesh, K. R., Alexandropoulos, D. I., Xie, H., & Dunbar, K. R.

citation count

  • 6

complete list of authors

  • Vignesh, Kuduva R||Alexandropoulos, Dimitris I||Xie, Haomiao||Dunbar, Kim R

publication date

  • April 2020